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In the article, relates to the methods of production of hydrogen for vehicles equipped with fuel cells. Discussed practical possibilities hydrogenization of motor transport in Poland by the use of cars and public buses equipped with fuel cells. The territorial accessibility for hydrogen vehicles is determined by the availability of hydrogen refueling infrastructure, in the first place along the TEN-T network. As a result of verification, under Polish conditions, of the original method developed for determining the initial location of the hydrogen refueling station in Poland, in the pre-commercial phase (2020- 2030), the said location has been indicated along with the order of investment, taking into account above all the freedom to move around Poland of cars powered by hydrogen visiting Poland and transiting our country between other EU countries.